Depending on the order of the units added, the odds displayed can change (drastically). This makes it (even more) difficult sometimes to figure out if an attack is possible or not.
As an example:



All three times, the same troops are attacking. Each time the modified strength of the attackers are different. Usually the modified strength of the defender also changes.
In the screenshots you can also see that if the GR troopers are added last, the estimation adds a stack penalty.
Pretty much all the values change - not just the total, but also the values for the individual unit. So the readiness modifier, morale, leaders, etc change.
Again, I don't know if this has an actual effect on the battle.